Primary Secondary Reforming Catalyst
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Primary Secondary Reforming Catalyst

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Primary Steam-reforming Catalyst

Features & Scope of Application  

Z111-6YQ  and  CN-16YQ  are  sintered  type  steam-reforming  catalysts  for  gaseous  hydrocarbon,  with nickel  as  their  active  ingredient,  alumina  as  their support,  rare  earth  oxide  and  basic  oxide  as  their promoter.    They    have    more    reasonable    outer appearance structure to improve strength and outer surface area, more reasonable micro pore structure to improve the effective utilization of inner surface area, adding rare earth oxide and basic oxide as promoter to advance catalyst activity at low temperature and anti-carbon formation ability.

image1

Z111-6YQ and CN- 16YQ are applied in chemical fertilizer/methanol/hydrogen production plants, etc. utilizing natural gas/oil associated gas/refinery off-gas/coke-oven gas, etc. as feedstock. Z111- 6YQ is usually loaded in the upper section of the primary reformer tube and CN- 16YQ is loaded in the lower section. So far, Z111-6YQ and CN- 16YQ have been used in more than 65 sets of ammonia and methanol plants with production capacity of 1000 tons per day.


Z111-6YQTechnical Specifications

Chemical Composition

NiO

wt.%

≥14

CaO

wt.%

Proprietary

Rare Earth Oxide

wt.%

Proprietary

Al2O3

wt.%

Balance

Si

wt.%

<0.1


Physical Properties


Catalyst form

Six-holes cylinder with both domed

Size

mm

O.D. × H ×Hole D: Ф 16×16×3.5

Bulk density

kg/l

0 .95~1.05

Crush strength

N/gr

450

Operation Conditions



Operating temperature range

Inlet:430~650

Outlet:600~980

pressure

MPa

Normal pressure~5.0

Steam/carbon ratio


≥1.8

Carbon space velocity

h-1

500~3000



CN-16YQTechnical Specifications

Chemical Composition

NiO


wt%


≥14


H2/Oil ratio (v/v)

wt%


Proprietary


Hydrogen in feed gas

wt%


Balance


LHSV

wt%


<0.1



Physical Properties

Catalyst form Size

mm

Six-holes cylinder with both domed O.D. × H ×Hole D: Ф16×16×3.5

Bulk density

kg/l

0.95~1.05

Granular radial crush strength (avg.)

N/gr

≥450


Operation Conditions

Operating temperature range

Inlet:430~650;   Outlet:600~980

pressure

MPa

Normal pressure~5.0

Steam/carbon ratio


≥1.8

Carbon space velocity

h-1

500~3000


Secondary Steam-reforming Catalyst

Features & Scope of Application

Z205  and  CN-20  are  used  in  chemical  fertilizer, methanol, hydrogen production plants, etc. utilizing natural gas/oil associated gas/refinery off-gas/coke-oven  gas,  etc.  as  feedstock,  and  widely  applied  in secondary  reformers,  auto-thermal  reforming  and pure oxygen secondary reforming. Z205 is sintered type  catalyst  of  high  temperature  and  air  scour resistance, with a little amount of nickel as its active ingredient and calcium aluminate as its support, loaded in the upper section of secondary reformer to protect catalyst from lower section;

image1

CN-20  is  catalyst  with  nickel  as  its  active  ingredient,  calcium  aluminate  as  its support, loaded in the lower section of secondary reformer. Z205 and CN-20 have more reasonable outer appearance structure to improve strength, more reasonable micro pore structure to improve the effective utilization of inner surface area, adding basic oxide as promoter to advance catalyst active stability. So far, Z205 and CN-20 have been used in more than 60 sets of ammonia and methanol plants with production capacity of 1000 tons per day.


Z205 Technical Specifications

Chemical Composition

NiO

wt%

≥5

CaO

wt%

Proprietary

Al2O3

wt% Balance

Si

wt%

≤0.2


Physical Properties

Outer appearance


Rasching ring or other sizes

Size

mm

Ф25×10×16~18

Bulk density

kg/l

0.9~1.0

Crush strength

N/gr

≥ 450


Operation Conditions

Operation temperature

550~1450

Steam/carbon ratio


2.0~5.0(based on inlet of PSR)



CN-20 Technical Specifications

Chemical Composition

NiO

wt%

≥14

CaO

wt%

Proprietary

Al2O3

wt%

Balance

Si

wt%

≤0.2


Physical Properties

Outer appearance


Rasching ring or other sizes

Size

mm

Ф19×9×19

Bulk density

kg/l

0.8~0.9

Crush strength

N/gr

≥450


Operation Conditions

Operation temperature

550~1450

Steam/carbon ratio


2.0~5.0(based on inlet of PSR)

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