ZSM-5 Zeolite/molecular sieves
Synthesis of ZSM-5 by direct method
ZSM-5 zeolite is synthesized directly by reacting soluble glass with aluminium sulphate to ZSM-5 zeolite, not using organic amine.
ZSM-5 zeolite has been used as the parent of alkylationm, isomeration, aromatization and dewaxing catalysts and so on.
ZSM-5 zeolite, characteristic of the simpler synthesis process, stabler quality, free of pollution, less cost, better hydrothermally.
ZSM-5 zeolite won the second place of the State Invention Prize of china.
| SiO2/Al2O3 mol/mol | Nominal Cation Form | Na2O m/m % | Crystallinity % | Surface Area m2/g | |
| 18.4 | H | 0.04 | 96 | 350 | |
| 21 | H | 0.03 | 95 | 352 | |
| 26 | Na | 7.5 | 90 | 330 | |
| 26 | H | 0.05 | 96 | 348 | |
| 27(nano) | H | 0.08 | 92 | 350 | |
| 26 | H | 0.05 | 83 | / | |
| 26 | Fe | 0.05 | 85 | / | |
| 27 | Fe | 0.08 | 87 | / | |
| 26 | Cu | 0.08 | 83 | / | |
| 38 | Na | 7.5 | 92 | / | |
| 38 | H | 0.08 | 96 | 352 | |
| 46 | Na | / | 90 | 330 | |
| 46 | H | 0.05 | 95 | 355 | |
| 60 | H | 0.05 | 94 | 350 | |
| 70 | H | 0.04 | 96 | 352 | |
| 85 | H | 0.04 | 94 | 350 | |
| 120 | H | 0.04 | 98 | 357 | |
| 135 | H | 0.05 | 96 | 352 | |
| 145 | H | 0.05 | 96 | 354 | |
| 175 | H | 0.04 | 97 | 355 | |
| 201 | H | 0.05 | 98 | 352 | |
| 203 | H | 0.05 | 98 | 350 | |
| 300 | H | 0.04 | 98 | 356 | |
| 360 | H | 0.04 | 97 | 355 | |
| 420 | H | 0.04 | 94 | 360 | |
| 470 | H | 0.04 | 94 | 356 | |
| 505 | H | 0.03 | 94 | 357 | |
| 860 | H | 0.03 | 94 | 354 | |
| 1520 | H | 0.03 | 95 | 358 |
Zeolite ( Chemical Composition)
| (SiO2/Al2O3)=25 | (SiO2/Al2O3)=38 | (SiO2/Al2O3)=50 | |
| Al2O3 | 5.0~5.5% | 3.8~3.9% | 2.3~2.5% |
| SiO2 | 80.0~85.0% | 85.0~86.0% | 86.0~87.0% |
Zeolite (Adsorption)
| (Adsorbent) | (N-hexane) | (Cyclohexane) | (Water) |
| (SiO2/Al2O3)=25 | 9.5~10.5% | 2.1~2.5% | 11.0~12.0% |
| (SiO2/Al2O3)=38 | 9.5~10.5% | 1.9~2.3% | 9.0~10.0% |
| (SiO2/Al2O3)=50 | 9.0~10.0% | 1.5~2.0% | 7.0~8.0% |
Main Applications of ZSM-5 Molecular Sieve
1. In fluidized bed catalytic cracking (FCC), the addition of ZSM-5 molecular sieve to FCC catalysts can increase the octane rating of gasoline and the olefin content in the gas phase.
2. Adding ZSM-5 molecular sieve as a component in FCC catalysts can reduce the olefin content in gasoline.
3. Residue catalytic cracking catalysts also incorporate ZSM-5 molecular sieve.
4. A key component in propylene production aids.
5. Extensively used in the chemical industry for shape-selective catalysis, such as in catalysts for para-xylene and xylene isomerization.
6. In environmental protection, for the adsorption and extraction of organic compounds from water; hydrophobic high-silica ZSM-5 zeolites coated on the surface of honeycomb channels to form adsorption wheels for the purification and adsorption treatment of volatile organic compounds (VOCs).
7. Used as a catalyst for low-hydrocarbon alkylation, isomerization, aromatization, and wax dewaxing; f
8. Suitable for esterification catalysts; hydration catalysts; etherification catalysts.
9. Agricultural soil remediation: saline-alkali land management; soil remediation for chemical pesticide contamination, heavy metal pollution, etc.10. Additive for high-end cosmetics.
ZSM-5 Zeolite/molecular sieves
Synthesis of ZSM-5 by direct method
ZSM-5 zeolite is synthesized directly by reacting soluble glass with aluminium sulphate to ZSM-5 zeolite, not using organic amine.
ZSM-5 zeolite has been used as the parent of alkylationm, isomeration, aromatization and dewaxing catalysts and so on.
ZSM-5 zeolite, characteristic of the simpler synthesis process, stabler quality, free of pollution, less cost, better hydrothermally.
ZSM-5 zeolite won the second place of the State Invention Prize of china.
| SiO2/Al2O3 mol/mol | Nominal Cation Form | Na2O m/m % | Crystallinity % | Surface Area m2/g | |
| 18.4 | H | 0.04 | 96 | 350 | |
| 21 | H | 0.03 | 95 | 352 | |
| 26 | Na | 7.5 | 90 | 330 | |
| 26 | H | 0.05 | 96 | 348 | |
| 27(nano) | H | 0.08 | 92 | 350 | |
| 26 | H | 0.05 | 83 | / | |
| 26 | Fe | 0.05 | 85 | / | |
| 27 | Fe | 0.08 | 87 | / | |
| 26 | Cu | 0.08 | 83 | / | |
| 38 | Na | 7.5 | 92 | / | |
| 38 | H | 0.08 | 96 | 352 | |
| 46 | Na | / | 90 | 330 | |
| 46 | H | 0.05 | 95 | 355 | |
| 60 | H | 0.05 | 94 | 350 | |
| 70 | H | 0.04 | 96 | 352 | |
| 85 | H | 0.04 | 94 | 350 | |
| 120 | H | 0.04 | 98 | 357 | |
| 135 | H | 0.05 | 96 | 352 | |
| 145 | H | 0.05 | 96 | 354 | |
| 175 | H | 0.04 | 97 | 355 | |
| 201 | H | 0.05 | 98 | 352 | |
| 203 | H | 0.05 | 98 | 350 | |
| 300 | H | 0.04 | 98 | 356 | |
| 360 | H | 0.04 | 97 | 355 | |
| 420 | H | 0.04 | 94 | 360 | |
| 470 | H | 0.04 | 94 | 356 | |
| 505 | H | 0.03 | 94 | 357 | |
| 860 | H | 0.03 | 94 | 354 | |
| 1520 | H | 0.03 | 95 | 358 |
Zeolite ( Chemical Composition)
| (SiO2/Al2O3)=25 | (SiO2/Al2O3)=38 | (SiO2/Al2O3)=50 | |
| Al2O3 | 5.0~5.5% | 3.8~3.9% | 2.3~2.5% |
| SiO2 | 80.0~85.0% | 85.0~86.0% | 86.0~87.0% |
Zeolite (Adsorption)
| (Adsorbent) | (N-hexane) | (Cyclohexane) | (Water) |
| (SiO2/Al2O3)=25 | 9.5~10.5% | 2.1~2.5% | 11.0~12.0% |
| (SiO2/Al2O3)=38 | 9.5~10.5% | 1.9~2.3% | 9.0~10.0% |
| (SiO2/Al2O3)=50 | 9.0~10.0% | 1.5~2.0% | 7.0~8.0% |
Main Applications of ZSM-5 Molecular Sieve
1. In fluidized bed catalytic cracking (FCC), the addition of ZSM-5 molecular sieve to FCC catalysts can increase the octane rating of gasoline and the olefin content in the gas phase.
2. Adding ZSM-5 molecular sieve as a component in FCC catalysts can reduce the olefin content in gasoline.
3. Residue catalytic cracking catalysts also incorporate ZSM-5 molecular sieve.
4. A key component in propylene production aids.
5. Extensively used in the chemical industry for shape-selective catalysis, such as in catalysts for para-xylene and xylene isomerization.
6. In environmental protection, for the adsorption and extraction of organic compounds from water; hydrophobic high-silica ZSM-5 zeolites coated on the surface of honeycomb channels to form adsorption wheels for the purification and adsorption treatment of volatile organic compounds (VOCs).
7. Used as a catalyst for low-hydrocarbon alkylation, isomerization, aromatization, and wax dewaxing; f
8. Suitable for esterification catalysts; hydration catalysts; etherification catalysts.
9. Agricultural soil remediation: saline-alkali land management; soil remediation for chemical pesticide contamination, heavy metal pollution, etc.10. Additive for high-end cosmetics.
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